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18618-55-8
CeCl3•7H2O
5817010800CR
99%
606-073-0
Class 8
UN1759
PG II
Characteristic
Cerium(III) chloride (CeCl3), also known as cerous chloride or cerium trichloride, is a compound of cerium and chlorine. It is a white hygroscopic solid; it rapidly absorbs water on exposure to moist air to form a hydrate, which appears to be of variable composition, though the heptahydrate CeCl3·7H2O is known.
Chemical formula：CeCl3•7H2O
Molar mass：372.58 g/mol
Appearance：fine white powder
Density：3.97 g/cm3
Melting point：90 °C (decomposes)
Boiling point：1,727 °C (3,141 °F; 2,000 K)
Solubility in water：100 g/100 ml
Solubility：soluble in alcohol
Magnetic susceptibility (χ)：+2490.0•10−6 cm3/mol
Application
Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.
Characteristic
Cerium(III) chloride (CeCl3), also known as cerous chloride or cerium trichloride, is a compound of cerium and chlorine. It is a white hygroscopic solid; it rapidly absorbs water on exposure to moist air to form a hydrate, which appears to be of variable composition, though the heptahydrate CeCl3·7H2O is known.
Chemical formula：CeCl3•7H2O
Molar mass：372.58 g/mol
Appearance：fine white powder
Density：3.97 g/cm3
Melting point：90 °C (decomposes)
Boiling point：1,727 °C (3,141 °F; 2,000 K)
Solubility in water：100 g/100 ml
Solubility：soluble in alcohol
Magnetic susceptibility (χ)：+2490.0•10−6 cm3/mol
Application
Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.
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